CHEMISTRY OF THE ORGANOSILICON COMPOUNDS-165 2-TRIMETHYLSILYL-METHYL-1, 3-BUTADIENE-A VERSATILE BUILDING BLOCK FOR TERPENE SYNTHESIS

DOI: 10.1016/S0040-4020(01)88587-2

Source and publish data:

Tetrahedron p. 883 - 894 (1983)

Update date:2022-08-05

Topics:

Authors:

Sakurai, Hideki

Hosomi, Akira

Saito, Masaki

Sasaki, Koshi

Iguchi, Hirokazu

et al. et al.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4020(01)88587-2

Two types of synthetically useful reactions of 2-trimethylsilylmethyl-1,3-butadiene (7) are discussed.Reactions of 7 with acid chlorides, aldehydes, ketones and acetals activated by a Lewis acid give isoprenylated compounds, while 7 undergoes the Diels-Alder reaction whit dienophiles.High regiospecificity of the reaction qualifies 7 for a versatile building block of terpene synthesis.

Full text of DOI:10.1016/S0040-4020(01)88587-2

Products guided by the article

Product name:(4R,4aR,8aR)-4-Isopropyl-6-methyl-3,4,4a,5,8,8a-hexahydro-2H-naphthalen-1-one

Cas No:86391-43-7

R&D Labs maybe for 86391-43-7

Nantong Baokai Chemical Co., Ltd (Hangzhou Baokai Bio-Chemicals Co.,Ltd.)

Contact:+86-513-83886111

Address:No. 68 Suzhou road ,Binjiang Fine Chemical Industrial Park , Beixin town, Qidong city ,Jiangsu province
Jiangxi Global Natural Spice Co., Ltd.

website:https://www.jxhqxl.com/

Contact:+86-796-8106598

Address:No.89, Wenshan Road,South Industrial Park, Jishui County,Jiangxi Province
Changsha Nutritopper Bio Technology Co.,Ltd.

Contact:+86-731-87803543

Address:East 1st Street, Baima Road, Ningxiang County
Changsha Botaniex Inc.

Contact:(86) 731 88718666

Address:Room 1222, Unit 4, Building B, Shangcheng, No.47, Kaiyuan East Road.
Jiangsu Institute of Ecomones Co., Ltd

website:http://www.jsmone.com

Contact:+86-519-82821700

Address:95 Huanyuan N. Road, Jintan, Jiangsu, China

Relevant to this article

Cycloaddition reactions on activated exo-glycals

Doi:10.1016/j.tetasy.2005.06.027
(2005)
Chiral phosphine-olefin bidentate ligands in asymmetric catalysis: Rhodium-catalyzed asymmetric 1,4-addition of aryl boronic acids to maleimides

Doi:10.1002/anie.200501305
(2005)
Synthesis and transformations of 1,4-diethynyl-2-nitrobenzene

Doi:10.1007/s11172-006-0160-z
(2005)
High-Yield Direct Synthesis of a New Class of Tertiary Organolithium Derivatives of Polycyclic Hydrocarbons

Doi:10.1021/jo00166a008
(1983)
Self-assembly of a new series of quadruply hydrogen bonded heterotrimers driven by the donor-acceptor interaction

Doi:10.1016/j.tet.2005.07.075
(2005)
Chemo-enzymatic synthesis of (R)-and (S)-2-hydroxy-4-phenylbutanoic acid via enantio-complementary deracemization of (±)-2-hydroxy-4-phenyl-3- butenoic acid using a racemase-lipase two-enzyme system

Doi:10.1055/s-2005-871577
(2005)

Article Doi