AN EFFICIENT 1,3-ASYMMETRIC INDUCTION ACCOMPANIED WITH EPIMERIZATION AT THE 2-POSITION. STEREOSELECTIVE REDUCTION OF α-SUBSTITUTED β-KETO SULFOXIDES UNDER BASIC CONDITIONS

DOI: 10.1016/S0040-4039(00)81448-3

Source and publish data:

Tetrahedron Letters p. 503 - 506 (1983)

Update date:2022-08-02

Topics:

Authors:

Ogura, Katsuyuki

Fujita, Makoto

Inaba, Takashi

Takahashi, Kazumasa

Iida, Hirotada

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Article abstract of DOI:10.1016/S0040-4039(00)81448-3

An efficient 1,3-asymmetric induction was realized in the reduction of β-keto sulfoxides having various α-substituents with NaBH4 under basic conditions and, by the application of this induction, (R)-α-acetoxyphenylacetaldehyde was synthesized.

Full text of DOI:10.1016/S0040-4039(00)81448-3

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