Bridging Phenoxo-ligands in Dicopper(I) Complexes: Synthesis and Structure of Tetrakis(isocyanide)-bis(μ-phenoxo)-dicopper(I) Complexes

DOI: 10.1039/c39830000197

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 197 - 199 (1983)

Update date:2022-07-29

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Authors:

Pasquali, Marco

Fiaschi, Paolo

Floriani, Carlo

Gaetani-Manfredotti, Amelia

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Article abstract of DOI:10.1039/c39830000197

The reaction of CuCl with PhONa followed by the addition of RNC (R = cyclohexyl, p-tolyl) gave as thermally stable crystalline solids <(RNC)4Cu2(OPh)2> containing a dicopper(I) unit doubly bridged by two phenoxo-groups , with isocyanide ligands completing the tetraco-ordination around each copper <ν(C-N): R = p-tolyl, 2120 and 2145 cm^-1; R = cyclohexyl, 2130 and 2160 cm^-1>.

Full text of DOI:10.1039/c39830000197

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