Palladium-catalyzed oxidative cyclizations: Synthesis of dihydropyranones and furanones

DOI: 10.1021/jo051274d

Source and publish data:

Journal of Organic Chemistry p. 8478 - 8485 (2005)

Update date:2022-07-29

Topics: Catalyst Reaction Mechanism Substrate Oxidant

Authors:

Reiter, Maud

Turner, Hazel

Mills-Webb, Rebecca

Gouverneur, Veronique

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Article abstract of DOI:10.1021/jo051274d

A boron-mediated syn- and anti-stereoselective aldol reaction giving rise to various β-hydroxyenones was coupled to a Pd^(II)-mediated oxidative cyclization to give 2,3,6-trisubstituted syn- and antidihydropyranones in good yields. The Pd^(I

Full text of DOI:10.1021/jo051274d

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