Journal of Organic Chemistry p. 3631 - 3639 (1983)
Update date:2022-08-04
Topics:
Tamaru, Y.
Furukawa, Y.
Mizutani, M.
Kitao, O.
Yoshida, Z.
Highly diastereoselective α allylation of secondary and tertiary thioamides is achieved by making use of thio-Claisen rearrangement.From the correlation between the diastereoselectivities in products and the structures of allylating agents, the Z structures of secondary thioamide dianion (ca. 100percent Z) and tertiary thioamide anion (>97percent Z) are concluded.
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Doi:10.1248/cpb.31.1222
(1983)Doi:10.1021/jm701551j
(2008)Doi:10.1021/ic050817z
(2005)Doi:10.1021/om050721c
(2005)Doi:10.1021/ja054134u
(2005)Doi:10.1016/j.tetlet.2005.09.174
(2005)
