Activation of Arene Carbon-Hydrogen Bonds. Direct Electrophilic Aromatic Metallation with a Rhodium-Porphyrin Complex

DOI: 10.1039/c39830000478

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Journal of the Chemical Society. Chemical communications p. 478 - 479 (1983)

Update date:2022-08-04

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Authors:

Aoyama, Yasuhiro

Yoshida, Tohru

Sakurai, Ken-ichi

Ogoshi, Hisanobu

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Article abstract of DOI:10.1039/c39830000478

Anion exchange of octaethylporphyrinatorhodium(III) chloride with AgClO4 or AgBF4 results in the formation of a highly electrophilic Rh^III-porphyrin capable of direct metallation of arenes.

Full text of DOI:10.1039/c39830000478

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