Activation of Arene Carbon-Hydrogen Bonds. Direct Electrophilic Aromatic Metallation with a Rhodium-Porphyrin Complex

DOI: 10.1039/c39830000478

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 478 - 479 (1983)

Update date:2022-08-04

Topics:

Authors:

Aoyama, Yasuhiro

Yoshida, Tohru

Sakurai, Ken-ichi

Ogoshi, Hisanobu

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39830000478

Anion exchange of octaethylporphyrinatorhodium(III) chloride with AgClO4 or AgBF4 results in the formation of a highly electrophilic Rh^III-porphyrin capable of direct metallation of arenes.

Full text of DOI:10.1039/c39830000478

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:(octaethylporphyrinato)(4-methoxyphenyl)rhodium(III)

Cas No:87198-31-0

R&D Labs maybe for 87198-31-0

Tianjin Chemsyntech Chemical Co., Ltd

Contact:+86-22-60872258

Address:Haitai green industry base in Tianjin, K1,5-601
Taixing Joxin Bio-tec Co.,Ltd.

website:http://www.joxbio.com

Contact:86-523-87558858 87612088

Address:No.88, chengdong industrial park
Borun Chemical Co.,Ltd.

Contact:+86-574- 87178138; 87297407

Address:No. 809, Liudingxingzuo, cangsong road, Ningbo, China
Yancheng Smiling Imp & Exp Co., Ltd.

Contact:+86-515-83173586

Address:Rm1207, BLD#03, Phoenix Plaza, Juheng Road, Yancheng, Jiangsu, P.R. China
Shijiazhuang Sdyano Fine Chemical Co., Ltd

Contact:+86-311-89830448

Address:NO.48 Ta Nan Road,Yuhua District,Shijiazhuang,Hebei,China

Relevant to this article

Ruthenium(II) complexes derived from substituted cyclobutane and substituted thiazole Schiff base ligands: Synthetic, spectral, catalytic and antimicrobial studies

Doi:10.1081/SIM-200067062
()
Coordination chemistry of Ga(C₅Me₄Ph): Novel homoleptic d¹⁰ cluster complexes of palladium

Doi:10.1021/ic051658m
(2006)
Halogensubstituierte λ⁵- und λ³-Phosphorine

Doi:10.1016/S0040-4039(00)87967-8
(1983)
Doi:10.1021/ja01148a031
(1951)
SYNTHESIS AND HYPOGLYCEMIC ACTIVITY OF N-(5-CARBOALKOXYFURAN-2-SULFONYL)-N'-BUTYL UREA

Doi:10.1007/BF01150723
(1983)
Test of the Librational Entropy Mechanism of Elasticity of the Polypentapeptide of Elastine. Effect of Introducing a Methyl Groups at Residue 5.

Doi:10.1039/f19837900853
(1983)

Article Doi