SYNTHESIS, RAMAN AND NMR SPECTROSCOPY OF THE TRIMETALLIC COMPLEXES

DOI: 10.1016/0022-328X(83)80104-1

Source and publish data:

Journal of Organometallic Chemistry p. 17 - 30 (1983)

Update date:2022-08-04

Topics:

Authors:

Kretschmer, M.

Pregosin, P.S.

Favre, P.

Schlaepfer, C.W.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0022-328X(83)80104-1

Synthesis, Raman and NMR studies are presented for the new octahedral trimetallic complexes with composition , R = p-XC6H4; X = H, CH3O, F, Cl.Only the isomer containing the Cl3Sn-Ir-Hg-Cl fragment and trans phosphine ligands is observed.Force constants for the Ir-Sn and Ir-Hg bonds as well as 31P, 119Sn and 199Hg NMR data are reported.The presence of a spin-spin coupling constant of more than 40,000 Hz between the 199Hg and 119Sn atoms is shown to originate from a two-bond and not a one-bond interaction.

Full text of DOI:10.1016/0022-328X(83)80104-1

Products guided by the article

Product name:IrCl(SnCl₃)(HgCl)(CO)(P(C₆H₄Cl)3)2

Cas No:87225-20-5

R&D Labs maybe for 87225-20-5

Cartoon Ingredients Co., Ltd

website:http://www.cartoonchem.com/

Contact:+86-25-58074918

Address:Room 2109, RuiHua Business Center,315 South ZhongShan Road, Nanjing 210001, China
Changzhou LanXu Chemical Co.,ltd.(expird)

Contact:86-0519-86330911,13656129734,15261186386

Address:Room 524, Depart.Chemical, Changzhou Science and Eductaion town, Jiangsu, China;Factory: Haian Fine Chemical Industry Park,Nantong,Jiangsu,China
shanghai Tauto Biotech Co., Ltd

website:http://www.tautobiotech.com/en/index.htm

Contact:+86-21-51320588 ext. 8025

Address:No. 326, Aidisheng Rd , Zhangjiang Hi-tech Park, Shanghai , P.R.CHINA
Pale Palm Imex

Contact:+36(21)2523420

Address:Head office: 1102 Budapest, SZENT LASZLO TER 24/B. 1/1., HUNGARY / CHINA
Yicheng Goto Pharmaceuticals Co.,Ltd.

Contact:+86 710 3423122

Address:5th Floor,East Gate of Building #2,Servo-Industrial Park,1st Qilin Road,Xiangyang,Hubei,China

Relevant to this article

Reactions of N-(perfluorophenyl)carbonimidoyl dichloride with aromatic acids and their derivatives in the presence of AlCl₃. Formation of 2-(perfluorophenyl)isoindoline-1,3-dione and its derivatives

Doi:10.1007/s11178-005-0147-5
(2005)
Reaction of F Atoms with Methyl Nitrite. Infrared Spectroscopic Evidence for the Stabilization of FON in an Argon Matrix

Doi:10.1021/j150642a035
(1983)
Inhibition of lipid A stimulated activation of human dendritic cells and macrophages by amino and hydroxylamino monosaccharides

Doi:10.1002/anie.200604932
(2007)
Doi:10.1021/ja01114a025
(1953)
Novel reaction products from the hypervalent iodine oxidation of hydroxylated stilbenes and isoflavones

Doi:10.1039/b510240e
(2005)
Diastereoselective synthesis of the acyl side-chain and amino acid (2S,3R)-3-hydroxy-3-methylproline fragments of polyoxypeptin A

Doi:10.1055/s-2005-918924
(2005)

Article Doi