Journal of the Chemical Society. Chemical communications p. 276 - 277 (1983)
Update date:2022-08-05
Topics:
Watson, Patricia L.
Bis(pentamethylcyclopentadienyl)lutetium complexes Lu(η5-C5Me5)2R (R=Me, H) react at 20-50 deg C in hydrocarbon solvents with benzene, pyridine, the ylide CH2PPh3, and tetramethylsilane to give stable, isolatable products of C-H activation, i.e. metallation at a carbon of the reagent with extrusion of R-H.
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