THREO-SELECTIVE ALDOL CONDENSATIONS OF LITHIUM ENOLATES IN THE PRESENCE OF TRIALKYLBORANES

DOI: 10.1016/S0040-4039(00)87349-9

Source and publish data:

Tetrahedron Letters p. 2387 - 2390 (1982)

Update date:2022-09-26

Topics:

Authors:

Yamamoto, Yoshinori

Yatagai, Hidetaka

Maruyama, Kazuhiro

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Article abstract of DOI:10.1016/S0040-4039(00)87349-9

The reaction of preformed lithium enolates in the presence of trialkylboranes, such as Et₃B and n-Bu₃B, with aldehydes leads to product mixtures rich in the more stable threo aldol.

Full text of DOI:10.1016/S0040-4039(00)87349-9

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