Canadian Journal of Chemistry p. 1046 - 1050 (1986)
Update date:2022-08-02
Topics:
Bowie, John H.
DePuy, Charles H.
Sullivan, Sally A.
Bierbaum, Veronica M.
The flowing afterglow technique has been used to study the reactions of HO2- and HCO3- in the gas phase.The hydroperoxide ion reacts slowly with CO to form HO-, and oxidizes CO2, OCS, CS2, NO, SO2, CH3NCS in fast reactions to form CO3-, CO2S-, COS2-, NO2-, SO3-, CH3NCO2-, and CH3NCOS-, respectively.Reactions of HO2- with certain amides and esters provide synthetic routes for a number of interesting peracyl anions.One of these, the peroxyformate ion, HCO3-, reacts with CO and NO in slow oxidation reactions to form the formate ion HCO2-.It also forms HCO2- upon reaction with acetone and pivalaldehyde, perhaps by Baeyer-Villiger oxidation.
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