USE OF (2S,4R)-HYDROXYPROLINE DERIVATIVES AS LIGANDS IN CHIRAL COPPERI COMPLEXES

DOI: 10.1016/S0040-4039(00)86027-X

Source and publish data:

Tetrahedron Letters p. 3517 - 3520 (1983)

Update date:2022-08-02

Topics:

Authors:

Leyendecker, Francois

Laucher, Dominique

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Article abstract of DOI:10.1016/S0040-4039(00)86027-X

(2S)-Methoxymethyl-(4S)-thiotertiobutoxy-N-pivaloyl pyrrolidine 6 used as ligand in chiral cuprates led up to 75percent e.e. in the β-methylation of chalcone.The observed determinant role of the amide carbonyl group in the asymmetric recognition is explai

Full text of DOI:10.1016/S0040-4039(00)86027-X

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