
Journal of Organic Chemistry p. 573 - 575 (1984)
Update date:2022-08-05
Topics:
Vedejs, E.
Perry, D. A.
Sunlamp irradiation of phenacyl sulfides PhCOCH2SCHRR' affords thiocarbonyl compounds S=CRR' that can be trapped in high yield by using the nitronate CH3CH=N+(OTBS)O-; the heterocycle 3 resulting from 1,3-dipolar cycloaddition is cleaved rapidly by fluoride ion to give ketones or aldehydes.
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