Journal of Organic Chemistry p. 3086 - 3092 (2006)
Update date:2022-09-26
Topics:
Scott, Jeremy P.
Oliver, Steven F.
Brands, Karel M. J.
Brewer, Sarah E.
Davies, Antony J.
Gibb, Andrew D.
Hands, David
Keen, Stephen P.
Sheen, Faye J.
Reamer, Robert A.
Wilson, Robert D.
Dolling, Ulf-H.
A practical asymmetric synthesis of the γ-secretase inhibitor (-)-1 is described. As the key transformation, a highly diastereoselective intramolecular nitrile oxide cycloaddition forms the hexahydrobenzisoxazole core of 3 in four operations. Other aspect
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Doi:10.1016/j.bmcl.2006.01.080
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