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APPARENT CHELATION IN ALDOL REACTIONS OF CHIRAL (Me2CHO)3Ti-ENOLATES

DOI: 10.1016/S0040-4039(00)84131-3

Source and publish data:

Tetrahedron Letters p. 897 - 900 (1986)

Update date:2022-08-04

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Authors:

Nerz-Stormes, MaryellenNerz-Stormes, Maryellen

Thornton, Edward R.Thornton, Edward R.

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Article abstract of DOI:10.1016/S0040-4039(00)84131-3

Directed aldol reactions of chiral (Me2CHO)3Ti-enolates give the opposite diastereofacial selectivity compared with the corresponding boron enolates.This stereochemical reversal is best explained if the Ti reactions involve chelation

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Full text of DOI:10.1016/S0040-4039(00)84131-3

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