Tetrahedron Letters p. 897 - 900 (1986)
Update date:2022-08-04
Topics:
Nerz-Stormes, Maryellen
Thornton, Edward R.
Directed aldol reactions of chiral (Me2CHO)3Ti-enolates give the opposite diastereofacial selectivity compared with the corresponding boron enolates.This stereochemical reversal is best explained if the Ti reactions involve chelation
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