Journal of Organic Chemistry p. 731 - 733 (1984)
Update date:2022-08-05
Topics:
Kurth, Mark J.
Burns, Dennis H.
O'Brien, Michael J.
An efficient , stereoselective synthesis of octahydro-as-indacenone 2 , the carbocycle fragment of the antibiotic ikarugamycin , is described.The prominent step in the sequence is an intramolecular Diels-Alder reaction, which establishes the relative stereochemistry of 2.
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