Journal of Organic Chemistry p. 1001 - 1013 (1984)
Update date:2022-09-26
Topics:
Ireland, Robert E.
Dow, William C.
Godfrey, Jollie D.
Thaisrivongs, Suvit
Total synthesis of (+/-)-chamigrene and (+/-)-aphidicolin are described.Both approaches are based on the spiroannelation of related α-methylene ketones through first hetero-Diels-Alder condensation and then Claisen rearrangement of the derived allyl vinyl
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