Tetrahedron Letters p. 5087 - 5090 (1984)
Update date:2022-08-05
Topics:
Mase, Toshiaki
Sodeoka, Mikiko
Shibasaki, Masakatsu
Two synthetic routes to isocarbacyclin starting from furfural are described.One route involves the regioselective hydrogenation of the disubstituted olefin in the presence of two other olefinic double bonds, and the other includes the highly regioselective organocopper coupling with the allylic electrophile as a key step.
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