Carbon-14 Kinetic Isotope Effects and Mechanisms of Addition of 2,4-Dinitrobenzenesulfenyl Chloride to Substituted Styrenes-1-14C and Styrenes-2-14C

Article abstract of DOI:10.1021/ja00364a034

As the first reported examples of carbon isotope effects in simple electrophilic addition reactions we have measured the carbon-14 kinetic isotope effects in the addition of 2,4-dinitrobenzenesulfenyl chloride to a series of para-substituted α- and β-labe