Tetrahedron Letters p. 3353 - 3355 (2006)
Update date:2022-07-30
Topics:
Anderson, Thomas F.
Statham, Matthew A.J.
Carroll, Michael A.
Silanediols have been shown to be effective bioisosteres for the hydrated carbonyl group. Current methods for the formation of silanediols place a number of constraints on how and where this functionality may be used. A range of arylsilanes that would allow both the formation of arylsilanediols and that are also compatible with multi-step synthetic routes, have been investigated as possible precursors to silanediols. Through this study bis(2-furyl)silanes and, in particular, bis(2-thienyl)silanes have been identified as practical precursors to arylsilanediols.
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