Herboxidiene: Determination of absolute configuration by degradation and synthetic studies

DOI: 10.1016/S0040-4020(97)00021-5

Source and publish data:

Tetrahedron p. 2785 - 2802 (1997)

Update date:2022-08-05

Topics:

Authors:

Edmunds Edmunds

Trueb Trueb

Oppolzer

Cowley Cowley

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4020(97)00021-5

Degradation of the novel polyketide herbicide herboxidiene leads to useful fragments for further analogue synthesis and also enabled determination of the absolute configuration of the natural product via asymmetric synthesis of the respective fragments.

Full text of DOI:10.1016/S0040-4020(97)00021-5

Products guided by the article

Product name:(2S)-2-Hydroxy-3-methyl-bernsteinsaeuredimethylester

Cas No:89104-81-4

R&D Labs maybe for 89104-81-4

shijiazhuang baisheng chem co.; ltd

Contact:86-0311-80790826

Address:shijiazhuang hebei
Wuhan Soleado Technology Co.,Ltd.

Contact:86-2783341481 18971291927

Address:RM2405 Unit 1 Builing 1, Taiyin Tower, Changqing Road,Wuhan China
Laohekou Jinghong Chemical Co.,Ltd

Contact:+86-0710-3702747

Address:163.East，Huagong Road，Laohekou
Chinapeptides Co,. Ltd

Contact:+86-021-50792271

Address:Building 24A, 300 Chuantu Road, Chuansha, Pudong new area, Shanghai, China, 201202
Synasia Inc

Contact:17316303296

Address:240 Amboy Ave

Relevant to this article

Synthesis and biological evaluation of some Schiff bases of 4-amino-5-(4-methylsulfonyl)benzyl-2,4-dihydro-3H-[1,2,4]-triazole-3-thione

Doi:10.1007/s00044-012-0294-5
(2013)
Biotechnological Potential of Eugenol and Thymol Derivatives Against Staphylococcus aureus from Bovine Mastitis

Doi:10.1007/s00284-021-02344-9
(2021)
Electrochemical reactions of dihydroazaazulanones possessing a spirocyclic moiety: Ring cleavages of the spiro-rings, hydrogen migrations and formations of azaazulanones

Doi:10.3987/COM-01-9382
(2002)
Synthesis of 2,4-bis(aryloxy)-1,5-diarylpentane-1,5-diones by base-mediated tandem reaction

Doi:10.1055/s-0032-1316752
(2012)
Thermal, dielectrical properties and conduction mechanism of Cu(II) complexes of azo rhodanine derivatives

Doi:10.1016/j.materresbull.2015.01.063
(2015)
Approaches to α-amino acids via rearrangement to electron-deficient nitrogen: Beckmann and Hofmann rearrangements of appropriate carboxyl-protected substrates

Doi:10.3762/bjoc.8.161
(2012)

Article Doi