Ruthenium-catalyzed carbon-carbon bond formation via the cleavage of an unreactive aryl carbon-nitrogen bond in aniline derivatives with organoboronates

DOI: 10.1021/ja0713431

Source and publish data:

Journal of the American Chemical Society p. 6098 - 6099 (2007)

Update date:2022-08-04

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Authors:

Ueno, Satoshi

Chatani, Naoto

Kakiuchi, Fumitoshi

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Article abstract of DOI:10.1021/ja0713431

The RuH₂(CO)(PPh₃)₃-catalyzed reaction of 2-amino-6-methylacetophenone with phenylboronic acid 2,2-dimethyl-1,3-propanediol ester in refluxing toluene gave the corresponding phenylation product in 83% yield via aryl carbon

Full text of DOI:10.1021/ja0713431

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