ORGANOCUPRATE-INDUCED SUBSTITUTION OF THE ENOL OXYGEN MOIETY IN 2,2-DIFLUORO ENOL PHOSPHATES WITH ALLYL HALIDES: A NOVEL ROUTE TO gem-DIFLUOROOLEFINS FROM CHLORODIFLUOROMETHYL KETONES

DOI: 10.1016/S0040-4039(00)94166-2

Source and publish data:

Tetrahedron Letters p. 5657 - 5660 (1983)

Update date:2022-07-29

Topics:

Authors:

Ishihara, Takashi

Yamana, Masayuki

Ando, Teiichi

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Article abstract of DOI:10.1016/S0040-4039(00)94166-2

2,2-Difluoro-1-arylethenyl diphenyl phosphates, prepared from chlorodifluoromethyl ketones and diphenyl phosphite, reacted with dibutylcopperlithium and successively with various allyl halides to give allylated gem-difluoroolefins in moderate to excellent

Full text of DOI:10.1016/S0040-4039(00)94166-2

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