261. Construction of Large Carbocyclic Rings by Ireland-Claisen Rearrangement of O-Silylated Lactone Enolates: Synthesis of (+/-)-Muscone

DOI: 10.1002/hlca.19830660827

Source and publish data:

Helvetica Chimica Acta p. 2608 - 2614 (1983)

Update date:2022-08-03

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Authors:

Brunner, Rudolf K.

Broschberg, Hans-Juerg

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Article abstract of DOI:10.1002/hlca.19830660827

(+/-)-Muscone (5) has been synthesized from methyl 13-(chloroformyl)tridecanoate (6) in nine steps in an averall yield of 24 percent.The key steps involve an efficient transformation of the readily accessible 14-hydroxy-15-methyl-15-hexadecenoic acid (9)

Full text of DOI:10.1002/hlca.19830660827

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