Tetrahedron Letters p. 5877 - 5880 (1983)
Update date:2022-08-03
Topics:
Haufe, G.
Lacombe, S.
Laurent, A.
Rousset, C.
The addition of hydrogen fluoride to 1-phenyl-9-azabicyclo <6.1.0.>nonane gives two fluoroamines (52percent).The structures were established by n.m.r. techniques to be cis-2-fluoro-2-phenylcyclooctylamine and c-6-fluoro-c-2-phenylcyclooctyl-r-1-amine.A hydrido-bridged cation is likely the intermediate of the reaction.
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