THE STEREOCHEMISTRY OF THE PRODUCT HOMOALLYLIC ALCOHOLS FROM A MODIFIED GRIGNARD REACTION OF 3-PHENYLPROPEN-1-YL CHLORIDE AND BENZALDEHYDE

DOI: 10.1016/S0040-4039(00)81673-1

Source and publish data:

Tetrahedron Letters p. 1427 - 1428 (1983)

Update date:2022-08-04

Topics:

Authors:

Coxon, James, M.

Simpson, Gregory W.

Steel, Peter J.

Trenerry, V. Craige

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Article abstract of DOI:10.1016/S0040-4039(00)81673-1

The reaction of 3-phenylpropen-1-yl magnesiumchloride with benzaldehyde gave a mixture (7:3) of homoallylic alcohols (1) and (2) the relative configuration of which was determined from an X-ray analysis of the major epoxide formed by m-chloroperbenzoic acid oxidation of alcohol (1).

Full text of DOI:10.1016/S0040-4039(00)81673-1

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