Journal of Organometallic Chemistry p. 79 - 83 (2003)
Update date:2022-07-29
Topics:
Augé, Jacques
Lubin-Germain, Nadège
Marque, Sylvain
Seghrouchni, Latifa
Barbier allylation reaction of carbonyl compounds with allyl bromide was investigated using a catalytic amount of indium (0), indium (I) or indium (III) salts in the presence of a reducer and chlorotrimethylsilane (TMSCl). The Mn/TMSCl couple turned out to be the most efficient system to regenerate active indium in the allylation reaction of various carbonyl compounds including α- and β-oxygenated aldehydes.
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