Stereoselective Addition Reaction of Allylic Sulfides to Acetylenic Esters: E/Z Stereochemical Variations by Lewis Acid

DOI: 10.1021/jo00185a030

Source and publish data:

Journal of Organic Chemistry p. 1985 - 1989 (1984)

Update date:2022-08-05

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Authors:

Hayakawa, Kenji

Kamikawaji, Yoshimasa

Wakita, Akemi

Kanematsu, Ken

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Article abstract of DOI:10.1021/jo00185a030

The Lewis acid catalyzed addition reactions of allylic sulfides to methyl propiolate (MP) and dimethyl acetylenedicarboxylate (DMAD) have been investigated.The stereochemical outcome is considerably influenced by the Lewis acid.While the AlCl3-catalyzed r

Full text of DOI:10.1021/jo00185a030

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