Journal of the American Chemical Society p. 3728 - 3734 (1989)
Update date:2022-08-03
Topics: Asymmetric synthesis NMR spectroscopy Total synthesis Aldehyde Stereoselective Diastereoselective Organocatalysis Chiral Auxiliary
Miyashita, Masaaki
Suzuki, Toshio
Yoshikoshi, Akira
The stereoselective total synthesis of (-)-picritoxnin (1) and (-)-picrotin (2), starting from (+)-5β-hydroxycarvone (3), is described.Eight contiguous asymmetric centers on a cis-fused hydrindane ring system were stereoselectively prepared via three key
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