Metal-Catalyzed Stereospecific Michael Reaction Equivalent

DOI: 10.1021/jo00186a033

Source and publish data:

Journal of Organic Chemistry p. 2246 - 2252 (1984)

Update date:2022-08-03

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Authors:

Godleski, Stephen A.

Villhauer, Edwin B.

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Article abstract of DOI:10.1021/jo00186a033

The addition of nucleophiles to vinyl sulfide-allylic acetates mediated by (?-allyl)palladium intermediates has been shown to occur exclusively on the allyl terminus remote from sulfur, thereby effecting the equivalent to a Michael reaction.Due to the int

Full text of DOI:10.1021/jo00186a033

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