A Novel Type of Intramolecular Diels-Alder Reaction Involving Dienol Ethers: An Unusual Preference for a Boat Transition State in the Incipient Ring Formation

DOI: 10.1021/jo00185a071

Source and publish data:

Journal of Organic Chemistry p. 2079 - 2081 (1984)

Update date:2022-08-05

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Authors:

Koreeda, Masato

Luengo, Juan I.

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Article abstract of DOI:10.1021/jo00185a071

Cis and trans dienol ethers 2 and 3 have been stereospecifically synthesized and their intramolecular Diels-Alder reactions studied.While 3 did not cyclize upon prolonged heating, the cis dienol ether 2 underwent smooth cyclization through an unusual boat

Full text of DOI:10.1021/jo00185a071

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