A Novel Type of Intramolecular Diels-Alder Reaction Involving Dienol Ethers: An Unusual Preference for a Boat Transition State in the Incipient Ring Formation

DOI: 10.1021/jo00185a071

Source and publish data:

Journal of Organic Chemistry p. 2079 - 2081 (1984)

Update date:2022-08-05

Topics:

Authors:

Koreeda, Masato

Luengo, Juan I.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00185a071

Cis and trans dienol ethers 2 and 3 have been stereospecifically synthesized and their intramolecular Diels-Alder reactions studied.While 3 did not cyclize upon prolonged heating, the cis dienol ether 2 underwent smooth cyclization through an unusual boat

Full text of DOI:10.1021/jo00185a071

Products guided by the article

Product name:{(1S,3R)-3-[1-(tert-Butyl-diphenyl-silanyloxymethyl)-vinyl]-cyclopentyloxy}-acetic acid ethyl ester

Cas No:90150-52-0

R&D Labs maybe for 90150-52-0

Purestar Chem Enterprise Co.,Ltd

website:http://www.purestarchem.com

Contact:05722157374

Address:no235.huanchengdong Rd
ANHUI CHEM-BRIGHT BIOENGINEERING CO.,LTD

Contact:86-561-4080321

Address:No.8 Lieshan Industrial Zone of Huaibei
Richest Group Ltd.

Contact:+86 21 5017 5386

Address:No 999,Jiangyue Rd, Minhang Dist ,201114,Shanghai ,China
Innua Petrochem Ltd.

Contact:+1-284-4950244

Address:Box 3069, Road Town, Tortola, British Virgin Islands
Tianjin SPHINX SCIENTIFIC LAB.

Contact:+86-022-66211289

Address:Tianda high-tech Park. No.80,the 4th Avenue

Relevant to this article

A convenient synthesis of oxazolidinone derivatives linezolid and eperezolid from (S)-glyceraldehyde acetonide

Doi:10.1002/hc.20435
(2008)
Synthesis and reactions of poly[(ethoxysilylene)phenylenevinylene]s and chain-to-pendant energy transfer in the resulting polymer

Doi:10.1016/j.jorganchem.2006.03.021
(2006)
The preparation of 14-hydroxylated yohimbine and reserpine derivatives

Doi:10.1248/cpb.32.818
(1984)
Synthesis and biological activity of some 17a-substituted homolactones of androst-5-ene derivatives

Doi:10.1135/cccc20051387
(2005)
ADDITION REACTION OF SUBSTITUTED BENZENESULFINIC ACIDS TO N-PHENYLMALEIMIDE.

Doi:10.1246/bcsj.57.219
(1984)
A HIGHLY REGIO- AND STEREOSELECTIVE SYNTHESIS OF INTERNAL OLEFINS VIA AN ELIMINATION OF TRIMETHYLSTANNYL GROUP

Doi:10.1016/S0040-4039(00)99871-X
(1984)

Article Doi