A HIGHLY REGIO- AND STEREOSELECTIVE SYNTHESIS OF INTERNAL OLEFINS VIA AN ELIMINATION OF TRIMETHYLSTANNYL GROUP

DOI: 10.1016/S0040-4039(00)99871-X

Source and publish data:

Tetrahedron Letters p. 313 - 316 (1984)

Update date:2022-08-05

Topics:

Authors:

Murayama, Eigoro

Uematsu, Masahiro

Nishio, Hiroyuki

Sato, Tadashi

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Article abstract of DOI:10.1016/S0040-4039(00)99871-X

Internal reaction of secondary alkyltin(IV) compounds having thionium ion gave internal trans olefins with high yield and regio- and stereoselectivity via 1,5- or 1,6-transfer of a hydride β to the trialkylstannyl group.

Full text of DOI:10.1016/S0040-4039(00)99871-X

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