
Chemistry Letters p. 652 - 653 (2006)
Update date:2022-08-05
Topics:
Larios-Lopez, Leticiu
Navarro-Rodriguez, Damaso
Donnio, Bertrand
Guillon, Daniel
A series of bromoalkyloxy-substituted terphenylenes were synthesized through a Palladium cross-coupling reaction between arylboronic acids and bromoaryl derivatives. By DSC it was observed that these intermediates show a rich thermotropism in a wide range of temperature (110-180°C) and by X-ray diffraction it was determined that the liquid-crystalline nature corresponds to tilted type smectic mesophases (SmC, SmF/SmI, and a two-dimensional ordered tilted mesophase SmX). Copyright
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Doi:10.1021/jo01059a081
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(2006)