Formamidine anions in synthesis. The one-carbon homologation of aldehydes and ketones to nitriles

DOI: 10.1016/S0040-4039(00)73793-2

Source and publish data:

Tetrahedron Letters p. 5839 - 5842 (1993)

Update date:2022-07-31

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Authors:

Santiago

Meyers Meyers

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Article abstract of DOI:10.1016/S0040-4039(00)73793-2

Treatment of various carbonyl compounds with the carbanion of the 2-trimethylsilymethyl formamidine 2 gives the enamidine 3 which is readily transformed into the homologated nitriles 6.

Full text of DOI:10.1016/S0040-4039(00)73793-2

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