Steric Course of N5,N10-Methylenetetrahydrofolate Formation from Glycine by the Glycine Cleavage System in E. coli

DOI: 10.1021/ja00329a046

Source and publish data:

Journal of the American Chemical Society p. 4907 - 4910 (1984)

Update date:2022-08-04

Topics: Glycine Formation coli

Authors:

Aberhart, D. John

Russell, David J.

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Article abstract of DOI:10.1021/ja00329a046

The steric course of the conversion of glycine to 5,10-methylenetetrahydrofolate (5,10-CH2-H4folate) by the glycine cleavage system in E. coli has been elucidated. 2-H_re of glycine is the precursor of 11-H_re of 5,10-CH2-H4folate, and 2-H_si of glycine is the precursor of 11-H_si of 5,10-CH2-H4folate.The overall transformation is at least 78percent stereospecific (possibly higher).

Full text of DOI:10.1021/ja00329a046

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