Journal of the American Chemical Society p. 4907 - 4910 (1984)
Update date:2022-08-04
Aberhart, D. John
Russell, David J.
The steric course of the conversion of glycine to 5,10-methylenetetrahydrofolate (5,10-CH2-H4folate) by the glycine cleavage system in E. coli has been elucidated. 2-Hre of glycine is the precursor of 11-Hre of 5,10-CH2-H4folate, and 2-Hsi of glycine is the precursor of 11-Hsi of 5,10-CH2-H4folate.The overall transformation is at least 78percent stereospecific (possibly higher).
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