Organometallics p. 1310 - 1311 (1984)
Update date:2022-09-26
Topics:
Murray
Fackler Jr., John P.
Mazany, Anthony M.
The reaction of neat CH2X′X (X = Cl, X′ = Br, I) with [Au(CH2)2PPh2)2 initially gives the dinuclear Au(II) alkyl halide [Au(CH2)2PPh2]2(CH 2X)X′ that has been characterized in solution and by X-ray crystallography. Upon standing in this solvent the Au(II) alkyl halide adduct gives the bridging (methylene)gold(III) ylide dimer. The bridging (methylene)gold(III) complex undergoes a halogen substitution reaction with AgE (1:2) (E = CN, SCN, OOCPh). Diazomethane addition to [Au(CH2)2PPh2)2Br2 gives (μ-CH2)[Au(CH2)2PPh2] 2Br2.
View Moreshanghai jinshan pharmaceutical Co.,Ltd
Contact:021-57363011，13681638167
Address:No. 7966 Tingfeng Road,Jinshan,Shanghai,China
Contact:+86-511-88790000
Address:338 North Yushan Rd, Zhenjiang, Jiangsu 212016
Yangzhou Zhongbao Pharmaceutical Co.,Ltd
Contact:+86-514-88290838
Address:Jiangsu Baoying county economic develpment zone in baoying avenue91
Weifang Yukai Chemical Co.,Ltd.
website:http://www.yukaichem.com/en.html
Contact:+86-536-8865336
Address:binhai economic development zone，262737 shangdong，china
Shanghai Yudiao Chemistry Technology Co.,Ltd
Contact:0086-18964703211
Address:Building NO.5, NO.218,Rongtian Road,ganxiang town,Jinshan District,shanghai,201518,china
Doi:10.1016/j.ejmech.2006.03.012
(2006)Doi:10.1016/j.molcata.2005.12.018
(2006)Doi:10.1021/jo01123a004
(1955)Doi:10.1002/anie.200601529
(2006)Doi:10.1021/om0605581
(2006)Doi:10.1002/ejoc.200600304
(2006)
