Organometallics p. 1310 - 1311 (1984)
Update date:2022-09-26
Topics:
Murray
Fackler Jr., John P.
Mazany, Anthony M.
The reaction of neat CH2X′X (X = Cl, X′ = Br, I) with [Au(CH2)2PPh2)2 initially gives the dinuclear Au(II) alkyl halide [Au(CH2)2PPh2]2(CH 2X)X′ that has been characterized in solution and by X-ray crystallography. Upon standing in this solvent the Au(II) alkyl halide adduct gives the bridging (methylene)gold(III) ylide dimer. The bridging (methylene)gold(III) complex undergoes a halogen substitution reaction with AgE (1:2) (E = CN, SCN, OOCPh). Diazomethane addition to [Au(CH2)2PPh2)2Br2 gives (μ-CH2)[Au(CH2)2PPh2] 2Br2.
View Morewebsite:http://www.pribolab.com
Contact:+86 17657127611
Address:Building 21, MAX Business Hongwan, High-tech Zone, Qingdao
Jiaxing Trustworthy Import And Export Co.,Ltd
Contact:+86-573-82030555
Address:Room 1202, Unit B, Charming plaza,No.1558 East Zhongshan Road , Jiaxing City, Zhejiang Province, China.
suzhou BetterBioChem Co., Ltd.
website:http://www.betterbiochem.com
Contact:+86-18013506594
Address:No. 8 Building, 18 nong, Xi Yingnan Road, Pudong, Shanghai,China
Beijing Greenchem Technology Co.,Ltd. ( Panjin Greenchem Technology Co.Ltd .)
website:http://www.bjgreenchem.com/
Contact:+86-427-6515887
Address:301,302, 3rd Floor, Building C-7, Dongsheng Science Park, Northern Territory, Zhongguancun, No. 66, Xixiaokou Road, Haidian District, Beijing
Contact:+86-871-65217109
Address:132 Lanhei Road, Kunming Institute of Botany, Chinese Academy of Sciences
Doi:10.1016/j.ejmech.2006.03.012
(2006)Doi:10.1016/j.molcata.2005.12.018
(2006)Doi:10.1021/jo01123a004
(1955)Doi:10.1002/anie.200601529
(2006)Doi:10.1021/om0605581
(2006)Doi:10.1002/ejoc.200600304
(2006)
