Journal of Organometallic Chemistry p. 37 - 44 (1984)
Update date:2022-08-05
Topics:
Hawker, Darryl W.
Wells, Peter R.
With a variety of electrophilic reagents reaction occurs exclusively at the CH3-Sn bonds of <(CH3)3SN>4C and <(CH3)3Sn>3CH.While the inner Sn-C bonds remain intact, methyl groups may be progressively cleaved off, one from each of the trimethylstannyl groups; in the case of bromine a second Me group may be cleaved from each of the SnMe2Br groups.The various products were identified by 1H, 13C and 119Sn MNR spectroscopy.
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