Journal of Organic Chemistry p. 5616 - 5621 (1987)
Update date:2022-08-04
Topics:
Kashima, Choji
Tomotake, Atsushi
Omote, Yoshimori
By the photolysis of the ozonide derived from 1,4-benzodioxins, o-benzoquinones were obtained in moderate yields independent of the stability of o-benzoquinones and of the substituent groups, except the nitro group.Through the mechanistic studies, it was indicated that o-benzoquinones were formed through a radical decomposition pathway, while catechols were formed through an ionic decomposition pathway induced by acidic impurities.
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