Chemical evidence for peroxy radicals intermediacy in copper(II) reaction with hydroperoxides

DOI: 10.1016/S0040-4020(01)87222-7

Source and publish data:

Tetrahedron p. 7455 - 7462 (1993)

Update date:2022-08-03

Topics:

Authors:

Maumy, Michel

Capdevielle, Patrice

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4020(01)87222-7

Two unprecedented decompositions of tertiary hydroperoxides by Cu(II) in CH₃CN have been encountered : deoxygenation of 4- hydroperoxy cyclohexa 2,5- dienones 1 and 2 brings chemical support to the existence of intermediate peroxy radicals R-OO· 1′ and 2′.

Full text of DOI:10.1016/S0040-4020(01)87222-7

Products guided by the article

Product name:10β-chloro-estra-1(2),4(5)-dien-3,17-dione

Cas No:91413-55-7

R&D Labs maybe for 91413-55-7

Chengdu Green Young Biopharmaceutical INC

Contact:+86-28-85337952

Address:1-B-26,Tianhe Industry Park, No.1480 of Tianfu Road,Chengdu,P.R.China,610000
Weifang Adde Economic And Trade Co.,LTD.

Contact:86-536-8885548

Address:Room 1402,Wanda Plaza B Block,No.958,Yuanfei Road,Kuiwen District
Okeanos Tech.Co.,LTD

Contact:+86-10-62651721

Address:29 Yongxing Road, Daxing District,Beijing China
TIANJIN GST CHEMICAL TECHNOLOGY CO., LTD

Contact:+86-22-25210964

Address:Room. 208, No. -12-C, No. 13, Xinbei Road, Tanggu District, New Haixin Area, Tianjin City, China
Anhui Gusheng Import&Export CO.,LTD

Contact:86-551-63662296

Address:Jinzhai Road NO.162 ,hefei, china

Relevant to this article

Synthesis and properties of 2,3-dialkynyl-1,4-benzoquinones

Doi:10.1002/ejoc.200600081
(2006)
Enantioselective total synthesis of guanacastepene N using an uncommon 7-endo heck cyclization as a pivotal step

Doi:10.1021/ja0650504
(2006)
Design, synthesis, and biological evaluation of (E)-3-(4-methanesulfonylphenyl)-2-(aryl)acrylic acids as dual inhibitors of cyclooxygenases and lipoxygenases

Doi:10.1016/j.bmc.2006.08.008
(2006)
Large-scale synthesis of new pyranoid building blocks based on aldolase-catalysed carbon-carbon bond formation

Doi:10.1002/adsc.200800224
(2008)
PREPARATION OF CHIRAL SULFONES BY ASYMMETRIC ADDITION OF ARENESULFONYL CARBANIONS TO ACETONE

Doi:10.1246/cl.1984.611
(1984)
Divergent Synthesis of Cyclopropane-Containing Lead-Like Compounds, Fragments and Building Blocks through a Cobalt Catalyzed Cyclopropanation of Phenyl Vinyl Sulfide

Doi:10.1002/ejoc.201701030
(2017)

Article Doi