Chemical evidence for peroxy radicals intermediacy in copper(II) reaction with hydroperoxides

DOI: 10.1016/S0040-4020(01)87222-7

Source and publish data:

Tetrahedron p. 7455 - 7462 (1993)

Update date:2022-08-03

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Authors:

Maumy, Michel

Capdevielle, Patrice

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Article abstract of DOI:10.1016/S0040-4020(01)87222-7

Two unprecedented decompositions of tertiary hydroperoxides by Cu(II) in CH₃CN have been encountered : deoxygenation of 4- hydroperoxy cyclohexa 2,5- dienones 1 and 2 brings chemical support to the existence of intermediate peroxy radicals R-OO· 1′ and 2′.

Full text of DOI:10.1016/S0040-4020(01)87222-7

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