PREPARATION OF CHIRAL SULFONES BY ASYMMETRIC ADDITION OF ARENESULFONYL CARBANIONS TO ACETONE

DOI: 10.1246/cl.1984.611

Source and publish data:

Chemistry Letters p. 611 - 614 (1984)

Update date:2022-08-03

Topics:

Authors:

Akiyama, Takahiko

Shimizu, Makoto

Mukaiyama, Teruaki

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Article abstract of DOI:10.1246/cl.1984.611

In the presence of a chiral diamine, the magnesium salt of tolyl sulfone reacts with acetone at the α-carbon to afford the corresponding β-hydroxy adduct in good optical purity.

Full text of DOI:10.1246/cl.1984.611

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