
Journal of Organic Chemistry p. 4487 - 4494 (1984)
Update date:2022-07-30
Topics:
Dixon, Dabney White
Weiss, Randy H.
Oxidations of 1,2-bis(aminooxy)ethane (H2NOCH2CH2ONH2) and its phenyl substituted derivative (H2NOCHPhCH2ONH2) give a variety of products.Some are consistent with formation of the 1,4,2,3-dioxadiazene ring or a polymeric hyponitrite, while others derive from separate oxidation of the two ends of the hydroxylamine.Nitrogen yields are ca. 60percent in nickel peroxide oxidations and ca. 25percent in tert-butyl hypochlorite oxidations.
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