Tetrahedron p. 3519 - 3528 (1985)
Update date:2022-08-03
Topics:
Jaeger, Volker
Mueller, Ingrid
New variations for 1,3-dipolar nitrile oxide cycloadditions to reluctant dipolarophiles furan and 2-methylfuran are presented.The furoisoxazoline adducts 6 and 7 are shown to represent highly advanced, yet versatile precursors for derivatives of novel C6 and C7 amino sugar derivatives, accessible by subsequent highly stereoselective modification (addition of HO/OCH3 or HO/OH) and/or LiAlH4 reduction.
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