A Totally Synthetic Route to Lincosamine: Some Observations on the Diastereofacial Selectivity of Electrophilic Reactions on the Double Bonds of Various 5-(1-Alkenyl)arabinopyranosides

DOI: 10.1021/ja00291a029

Source and publish data:

Journal of the American Chemical Society p. 1274 - 1280 (1985)

Update date:2022-09-26

Topics:

Authors:

Danishefsky, Samuel J.

Larson, Eric

Springer, James P.

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Article abstract of DOI:10.1021/ja00291a029

Under the influence of boron trifluoride etherate, crotonaldehyde reacts with 1-methoxy-3-((trimethylsilyl)oxy)-4-(benzoyloxy)-1,3-butadiene to afford (E)-cis-2-(1-propenyl)-3-(benzoyloxy)-2,3-dihydro-4-pyrone.The latter is converted to (+/-)-β-methylinoc

Full text of DOI:10.1021/ja00291a029

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