LEWIS ACID CATALYSED CYCLOREVERSION OF COOKSON'S CAGE KETONES UNDER AMBIENT CONDITIONS: MODEL SYSTEM FOR LIGHT ENERGY CONVERSION

DOI: 10.1016/S0040-4039(01)80231-8

Source and publish data:

Tetrahedron Letters p. 2275 - 2278 (1984)

Update date:2022-08-02

Topics:

Authors:

Mehta, Goverdhan

Reddy, D. Sivakumar

Reddy, A. Veera

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Article abstract of DOI:10.1016/S0040-4039(01)80231-8

Design of 'push-pull' Cookson's cage ketones and their quantitative <2+2> cycloreversion to cis, syn, cis-triquinanes at room temp, under Lewis acid catalysis, is reported.This observation has promising ramifications on the utility of 1<*>2 system for reversible storage of solar energy.

Full text of DOI:10.1016/S0040-4039(01)80231-8

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