Tetrahedron Letters p. 5935 - 5938 (1994)
Update date:2022-09-26
Topics:
Khanna, Vibha
Tamilselvan, Pitchiah
Kalra, Swinder Jeet Singh
Iqbal, Javed
Cobalt(II)-porphyrin complex 1 and 2 catalyses the chlorination and sulfochlorination respectively of n-alkanes and cycloalkanes with sulfuryl chloride in benzene.The p-substituent of the benzene ring in the porphyrin complex 1 and 2 shows a remarkable chemoselectivity in these reactions.
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