Rearrangement of 1-Arylindoles to 5H-Dibenzazepines

DOI: 10.1016/0040-4020(94)01082-B

Source and publish data:

Tetrahedron p. 2091 - 2098 (1995)

Update date:2022-08-05

Topics:

Authors:

Tokmakov, Gennadii P.

Grandberg, Igor I.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0040-4020(94)01082-B

An unusual acid-catalyzed rearrangement of 1-arylindoles 1 to 5H-dibenzazepines 2 has been discovered.It can be used for the preparation of 2.The influence of the nature and the position of the substituents in the initial molecule 1 on the rearrangement is discussed.A possible mechanism of the reaction is suggested.A convenient method for preparation of 1-arylindoles 1c-k by means of arylation of 1-unsubstituted indoles with aryl halides by the Ullmann reaction is described.

Full text of DOI:10.1016/0040-4020(94)01082-B

Products guided by the article

Product name:10-Methyl-5H-dibenzoazepine

Cas No:92552-17-5

R&D Labs maybe for 92552-17-5

HUNAN CHEMAPI BIOLOGICAL TECHNOLOGY CO.,LTD.

Contact:+86-186-02659358

Address:1004, building 3, Wanke Jinsemaitianyuan, 498 Guitang Road, Yuhua District, Changsha City, Hunan Province, China
Suzhou JMS Chemical Co., Ltd.

Contact:+86-15995924277

Address:WuZhongOu suzhou new south road 89
Shanghai Massive Chemical Technology Co., Ltd.

website:http://www.massivechem.com/

Contact:+86 21 34943721

Address:Room 435, 4th floor, Building 9, No. 2568 Gudai Road,Minhang District, Shanghai,
Huludao Tianqi Shengye Chemical Co.,Ltd.

Contact:0086 429 2075777

Address:Area B,Shipbuilding Industry Park,Beigang District,Huludao City,Liaoning prov.,China
Antaeus Bio-technology Co., LTD(expird)

Contact:021-31252569

Address:shanghai pudong

Relevant to this article

Synthesis and coordination chemistry of an alkyne functionalised bis(pyrazolyl)methane ligand

Doi:10.1039/b613311h
(2006)
Synthesis of 3-hydroxy- and 3-carboxy-Δ²-isoxazoline amino acids and evaluation of their interaction with GABA receptors and transporters

Doi:10.1002/ejoc.200600628
(2006)
Thermolysis of O-allyl S-alkyl dithiocarbonates of codeine and isocodeine.

Doi:10.1248/cpb.36.1750
(1988)
1,4-benzodiazepines and 1,5-benzodiazocines XI. Synthesis and biological activity

Doi:10.1016/0223-5234(88)90007-4
(1988)
Bioorganic synthesis of end-capped anti-HIV peptides by simultaneous cyanocysteine-mediated cleavages of recombinant proteins

Doi:10.1016/j.bmc.2009.09.015
(2009)
Coordination modes of a Schiff base pentadentate derivative of 4-aminoantipyrine with cobalt(II), nickel(II) and copper(II) metal ions: Synthesis, spectroscopic and antimicrobial studies

Doi:10.3390/molecules14010174
(2009)

Article Doi