Chemical and Pharmaceutical Bulletin p. 1343 - 1345 (1991)
Update date:2022-08-05
Topics:
Saito
Nishida
Kubo
A transformation of (-)-saramycin A 3 to the saframycin Mx type compound 15 is described. Treating (-)-saframycin A 3 with selenium oxide in acetic acid afforded (-)-saframycin G 8, followed by catalytic reduction and regioselective oxidation to provide the hydroquinone 15.
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