Synthesis of saframycins. VI. The useful transformation of (-)-saframycin A to (-)-saframycin Mx type compound

DOI: 10.1248/cpb.39.1343

Source and publish data:

Chemical and Pharmaceutical Bulletin p. 1343 - 1345 (1991)

Update date:2022-08-05

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Authors:

Saito Saito

Nishida Nishida

Kubo Kubo

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Article abstract of DOI:10.1248/cpb.39.1343

A transformation of (-)-saramycin A 3 to the saframycin Mx type compound 15 is described. Treating (-)-saframycin A 3 with selenium oxide in acetic acid afforded (-)-saframycin G 8, followed by catalytic reduction and regioselective oxidation to provide the hydroquinone 15.

Full text of DOI:10.1248/cpb.39.1343

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