Canadian Journal of Chemistry p. 1092 - 1097 (1982)
Update date:2022-08-04
Topics:
Shahidi, Fereidoon
Tidwell, Thomas T.
Reaction of the 1,3-dioxole, 9, the 1,3-dioxan, 18, and the 1,3-dioxepin, 29, with tert-butoxy radicals gave evidence in each case for formation of the corresponding 1,1-dioxyethyl radicals.No conclusive evidence for formation of any of these radicals by cyclization of acetoxyaryl radicals could be obtained.Several of the 1,1-dioxyethyl radicals reacted by rearrangement.
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