Tetrahedron Letters p. 4665 - 4668 (1987)
Update date:2022-08-04
Topics:
Muzart, Jacques
Alkenes were converted into α,β-unsaturated carbonyl compounds using excess of tert.butylhydroperoxide and catalytic amounts of chromiumVI oxide at room temperature.Fair yields and conversions were obtained from Δ5-steroids while allylic oxidation of acyclic alkenes was less efficient.Epoxidation of the double bond, sometimes observed, remained a minor reaction pathway.
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(1994)
