Journal of the American Chemical Society p. 196 - 199 (1985)
Update date:2022-08-05
Topics: Synthesis Catalyst Enantioselective Nuclear magnetic resonance (NMR) spectroscopy Chromatography Reaction Conditions Ring Construction Chiral Auxiliary
Taber, Douglass F.
Petty, Eric H.
Raman, Krishna
Rhodium-catalyzed intramolecular C-H insertion (8->9) is shown to proceed with retention of absolute configuration.The product β-keto ester 9 is readily carried on to (+)-α-cuparenone (10).This represents a general strategy for the enantioselective
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(1985)
