Synthesis of dimethyl gloiosiphone A by way of palladium-catalyzed domino cyclization

DOI: 10.1021/jo062546v

Source and publish data:

Journal of Organic Chemistry p. 3667 - 3671 (2007)

Update date:2022-07-29

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Authors:

Doi, Takayuki

Iijima, Yusuke

Takasaki, Masaru

Takahashi, Takashi

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Article abstract of DOI:10.1021/jo062546v

(Chemical Equation Presented) The synthesis of a spiro[4.4]nonane skeleton by the palladium-catalyzed domino cyclization of a linear 7-methylene-2,10- undecadienyl acetate is described. The π-allylpalladium intermediate underwent intramolecular alkene ins

Full text of DOI:10.1021/jo062546v

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Product name:(E)-9-(4-methoxybenzyloxy)-7-methylene-5,5-di(phenylsulfonyl)-2,10-undecadienyl acetate

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